2008年夏季加拿大海盆净二氧化碳吸收量评估     

孙恒  高众勇  修鹏  卢鹏  陈立奇 《海洋学报(英文版)》2017,36(8):94-100

The third Chinese National Arctic Research Expedition(CHINARE) was conducted in the summer of 2008.During the survey,the surface seawater partial pressure of CO_2(pCO_2) was measured,and sea water samples were collected for CO_2 measurement in the Canada Basin.The distribution of pCO_2 in the Canada Basin was determined,the influencing factors were addressed,and the air-sea CO_2 flux in the Canada Basin was evaluated.The Canada Basin was divided into three regions:the ice-free zone(south of 77°N),the partially ice-covered zone(77°–80°N),and the heavily ice-covered zone(north of 80°N).In the ice-free zone,pCO_2 was high(320 to 368μatm,1 μatm=0.101 325 Pa),primarily due to rapid equilibration with atmospheric CO_2 over a short time.In the partially ice-covered zone,the surface pCO_2 was relatively low(250 to 270 μatm) due to ice-edge blooms and icemelt water dilution.In the heavily ice-covered zone,the seawater pCO_2 varied between 270 and 300 μatm due to biological CO_2 removal,the transportation of low pCO_2 water northward,and heavy ice cover.The surface seawater pCO_2 during the survey was undersaturated with respect to the atmosphere in the Canada Basin,and it was a net sink for atmospheric CO_2.The summertime net CO_2 uptake of the ice-free zone,the partially ice-covered zone and the heavily ice-covered zone was(4.14±1.08),(1.79±0.19),and(0.57±0.03) Tg/a(calculated by carbon,1Tg=10~(12) g),respectively.Overall,the net CO_2 sink of the Canada Basin in the summer of 2008 was(6.5±1.3) Tg/a,which accounted for 4%–10% of the Arctic Ocean CO_2 sink.  相似文献   

Rare earth element characteristics of the carboniferous Huanglong Formation dolomites in eastern Sichuan Basin,southwest China: Implications for origins of dolomitizing and diagenetic fluids     

《Marine and Petroleum Geology》2017

Marine dolostones of Carboniferous Huanglong Formation constitute major gas reservoir rocks in eastern Sichuan Basin. However, the investigation with respect to sources of dolomitizing and diagenetic fluids is relatively underexplored. The current study attempts to investigate the REE characteristics of dolomites using seawater normalization standard, and therefore discusses the origins of dolomitizing and diagenetic fluids, on the basis of continuous 47.33-m-long core samples from the second member of Huanglong Formation (C₂h₂) in eastern Sichuan Basin. Low Th, Sc, and Hf concentrations (0.791 × 10⁻⁶, 4.751 × 10⁻⁶, and 0.214 × 10⁻⁶, respectively), random correlation between total REE concentration (ΣREE) and Fe or Mn abundance, and seawater-like Y/Ho ratios (mean value of 45.612) indicate that the carbonate samples are valid for REE analysis. Based on petrographic characteristics, four dolomite types are identified, including micritic-sized dolomite (type Dol-1), fine-to medium-sized dolomite (type Dol-2), medium-to coarse-sized dolomite (type Dol-3), and coarse-to giant-sized saddle dolomite (type Dol-4). Dol-1 dolomites, characterized by positive Ce anomaly (mean value of 6.398), light REE (LREE) enrichment, and heavy REE (HREE) depletion with mean LREE/HREE ratio of 12.657, show micritic calcite-like REE patterns, indicating seawater origin of their dolomitizing fluids. Dol-1 dolomites were formed in sabkha environment whereas the dolomitizing fluids originated from evaporative brine water due to their micritic crystal sizes and tight lithology. Dol-2 dolomites, particularly subtype Dol-2a barely developing vuggy porosity, also show micritic calcite-like REE patterns, suggesting their dolomitizing fluids were seawater or seawater-derived fluids. This inference is confirmed by low Fe and Mn concentrations, which range from 651 μg/g to 1018 μg/g (mean value of 863 μg/g) and 65 μg/g to 167 μg/g (mean value of 105 μg/g), respectively, whereas homogenization temperatures (T_h, mean value of 103 °C) indicate that Dol-2 dolomites were formed under burial environment. Dol-3 dolomites, in form of cements of Dol-2 dolomites, show similar REE patterns to their host minerals (i.e., Dol-2 dolomites), indicating their parent source was possibly derived from Dol-2 dolomites. Dol-3 dolomites have high Fe and Mn concentrations with mean values of 3346 μg/g (ranging from 2897 μg/g to 3856 μg/g) and 236 μg/g (ranging from 178 μg/g to 287 μg/g), respectively, indicating the involvement of meteoric water. Meanwhile, it confirms that the dissolution in Dol-2 dolomites was caused by meteoric water leaching. Positive Eu anomalies (mean value of 1.406) in Dol-4 dolomites, coupled with high homogenization temperatures (mean value of 314 °C), suggest that Dol-4 dolomites precipitated from hydrothermal fluids. High Fe and Mn concentrations (mean values of 2521 μg/g and 193 μg/g, respectively) in Dol-4 dolomites likely results from interactions of hydrothermal fluids with deep burial clastic rocks.  相似文献   

Geochemistry,origin, and accumulation of petroleum in the Eocene Wenchang Formation reservoirs in Pearl River Mouth Basin,South China Sea: A case study of HZ25-7 oil field     

《Marine and Petroleum Geology》2017

The Pearl River Mouth Basin in the South China Sea has accumulated >2 km of Eocene sediments in its deep basin, and has become the exploration focus due to the recent discoveries of the HZ25-7 oil field in the Eocene Wenchang (E₂w) Formation. In this study, the geochemical characteristics of potential source rocks and petroleum in the HZ25-7 oil field are investigated and the possible origins and accumulation models developed. The analytical results reveal two sets of potential source rocks, E₂w and Enping (E₂e) formations developed in the study area. The semi-deep-to-deep lacustrine E₂w source rocks are characterized by relatively low C₂₉ steranes, low C₁₉/C₂₃ tricyclic terpane (<0.6), low C₂₄ tetracyclic terpane/C₃₀ hopane (<0.1), low trans-trans-trans-bicadinane (T)/C₃₀ hopane (most <2.0), and high C₃₀ 4-methyl sterane/ΣC₂₉ sterane (>0.2) ratios. In contrast, the shallow lacustrine and deltaic swamp-plain E₂e source rocks are characterized by relatively high C₂₉ steranes, high C₁₉/C₂₃ tricyclic terpane (>0.6), high C₂₄ tetracyclic terpane/C₃₀ hopane (>0.1), variable yet overall high T/C₃₀ hopane, and low C₃₀ 4-methyl sterane/ΣC₂₉ sterane (<0.2) ratios. The relatively low C₁₉/C₂₃ tricyclic terpane ratios (mean value: 0.39), low C₂₄ tetracyclic terpane/C₃₀ hopane ratios (mean value: 0.07), high C₃₀ 4-methyl sterane/ΣC₂₉ sterane ratios (mean value: 1.14), and relatively high C₂₇ regular sterane content of petroleum in the HZ25-7 oil field indicate that the petroleum most likely originated from the E₂w Formation mudstone in the Huizhou Depression. One stage of continuous charging is identified in the HZ25-7 oil field; oil injection is from 16 Ma to present and peak filling occurs after 12 Ma. Thin sandstone beds with relatively good connectivity and physical properties (porosity and permeability) in the E₂w Formation are favorable conduits for the lateral migration of petroleum. This petroleum accumulation pattern implies that the E₂w Formation on the western and southern margins of the Huizhou Depression are favorable for petroleum accumulation because they are located in a migration pathway. Thus exploration should focus in these areas in the future.  相似文献   

A 3D structural analysis of the Goliat field,Barents Sea,Norway     

《Marine and Petroleum Geology》2017

The Goliat field consists of Middle to Late Triassic reservoirs which exploit an elongate anticline (the Goliat anticline) in the hanging wall of the Troms-Finnmark Fault Complex (TFFC), offshore Norway. The area is affected by a dense network of multiple trending fault populations which historically have inhibited seismic resolution owing to persistent fault shadow. Seismic investigations utilising a multi-azimuth three-dimensional survey (EN0901) allow much crisper delineation of seismic features previously unattainable by vintage single-azimuth surveys. Three dominant fault populations are identified in the area, two of which parallel TFFC segments, the Alke–Goliat (WSW–ENE) and the Goliat–Tornerose (NNE–SSW) segments. The Goliat field is located within a zone of intersection between both segments. A third E–W trending fault population, the Hammerfest Regional population, is likely influenced by the offshore extension of the Trollfjord-Komagelv Fault Complex (TKFZ). A local NW–SE trending fault population, the Goliat Central, affects the Goliat anticline and partitions Alke–Goliat and Goliat–Tornerose subsidiary faults resulting in curvilinear traces. Several cross-cutting relationships between fault populations are observed and may provide fluid compartmentalisation in the reservoirs. Compilation of regional transects and the EN0901 survey provides new insight into the evolution of the Goliat anticline which is underlain by a fault-bound basement terrace that became established in the Late Palaeozoic. The structure is interpreted to have formed due to vertical segmentation of the TFFC and cores the overlying broad anticline. The western limb of the Goliat anticline likely formed by differential compaction, whereas the eastern limb is primarily a result of hanging wall roll-over linked to variable listric to ramp-flat-ramp fault geometry. Rifting took place in the Palaeozoic (Carboniferous to Permian?), and in the Mesozoic, possibly as early as the Late Triassic, with a major event in the Late Jurassic to Early Cretaceous. Minor reactivations continued into the Late Cretaceous, and possibly the Early Cenozoic. Mesozoic syn-kinematic geometries in the hanging wall of the Goliat–Tornerose TFFC segment are consistent with deposition during up section propagation of a blind fault, over which, a monocline was established and later breached. Jogs (abrupt orientation changes) in fault traces, transverse folds (associated with displacement maxima/minima) and vertical fault jogs suggest the TFFC existed as a greater number of segments prior to amalgamation during the Late Triassic to Jurassic. A phase of Barremian inversion created local compression structures above blind extensional faults, and deeper seated buttressing against large faults. Polygonal faults affect the Late Cretaceous to Early Cenozoic successions.  相似文献   

Influence of natural fractures on gas accumulation in the Upper Triassic tight gas sandstones in the northwestern Sichuan Basin,China     

《Marine and Petroleum Geology》2017

The Upper Triassic Xujiahe Formation in the northwestern Sichuan Basin, China, is a typical tight gas sandstone reservoir that contains natural fractures and has an average porosity of 1.10% and air permeability less than 0.1 md because of compaction and cementation. According to outcrops, cores and image logs, three types of natural fractures, namely, tectonic, diagenetic and overpressure-related fractures, have developed in the tight gas sandstones. The tectonic fractures include small faults, intraformational shear fractures and horizontal shear fractures, whereas the diagenetic fractures mainly include bed-parallel fractures. According to thin sections, the microfractures also include tectonic, diagenetic and overpressure-related microfractures. The diagenetic microfractures consist of transgranular, intragranular and grain-boundary fractures. Among these fractures, intraformational shear fractures, horizontal shear fractures and small faults are predominant and significant for fluid movement. Based on the Monte Carlo method, these intraformational shear fractures and horizontal shear fractures improve the reservoir porosity and permeability, thus serving as an important storage space and primary fluid-flow channels in the tight sandstones. The small faults may provide seepage channels in adjacent layers by cutting through layers. In addition, these intragranular and grain-boundary fractures increase the connectivity of the tight gas sandstones by linking tiny pores. The tectonic microfractures improve the seepage capability of the tight gas sandstones to some extent. Low-dip angle fractures are more abundant in the T₃X³ member than in the T₃X² and T₃X⁴ members. The fracture intensities of the sandstones in the T₃X³ member are greater than those in the T₃X² and T₃X⁴ members. The fracture intensities do not always decrease with increasing bed thickness for the tight sandstones. When the bed thickness of the tight sandstones is less than 1.0 m, the fracture intensities increase with increasing bed thickness in the T₃X³ member. Fluid inclusion evidence and burial history analysis indicate that the tectonic fractures developed over three periods. The first period was at the end of the Triassic to the Early Jurassic. The tectonic fractures developed during oil generation but before the matrix's porosity and permeability reduced, which suggests that these tectonic fractures could provide seepage channels for oil migration and accumulation. The second period was at the end of the Cretaceous after the matrix's porosity and permeability reduced but during peak gas generation, which indicates that gas mainly migrated and accumulated in the tectonic fractures. The third period was at the end of the Eogene to the Early Neogene. The tectonic fractures could provide seepage channels for secondary gas migration and accumulation from the Upper Triassic Xujiahe Formation into the overlying Jurassic Formation.  相似文献   

Kilometer-scale fault-related thermal anomalies in tight gas sandstones     

《Marine and Petroleum Geology》2017

Upper Carboniferous sandstones make one of the most important tight gas reservoirs in Central Europe. This study integrates a variety of geothermometers (chlorite thermometry, fluid inclusion microthermometry and vitrinite reflection measurements) to characterize a thermal anomaly in a reservoir outcrop analog (Piesberg quarry, Lower Saxony Basin), which is assumed responsible for high temperatures of circa 300 °C, deteriorating reservoir quality entirely. The tight gas siliciclastics were overprinted with temperatures approximately 90–120 °C higher compared to outcropping rocks of a similar stratigraphic position some 15 km to the west. The local temperature increase can be explained by circulating hydrothermal fluids along the fault damage zone of a large NNW-SSE striking fault with a displacement of up to 600 m in the east of the quarry, laterally heating up the entire exposed tight gas sandstones. The km-scale lateral extent of this fault-bound thermal anomaly is evidenced by vitrinite reflectance measurements of meta-anthracite coals (VR_rot ∼ 4.66) and the temperature-related diagenetic overprint. Data suggest that this thermal event and the associated highest coalification was reached prior to peak subsidence during Late Jurassic rifting (162 Ma) based on K-Ar dating of the <2 μm fraction of the tight gas sandstones. Associated stable isotope data from fluid inclusions, hosted in a first fracture filling quartz generation (T ∼ 250 °C) close to lithostatic fluid pressure (P ∼ 1000 bars), together with authigenic chlorite growth in mineralized extension fractures, demonstrate that coalification was not subject to significant changes during ongoing burial. This is further evidenced by the biaxial reflectance anisotropy of meta-anthracite coals. A second event of quartz vein formation occurred at lower temperatures (T ∼ 180 °C) and lower (hydrostatic) pressure conditions (P ∼ 400 bars) and can be related to basin inversion. This second quartz generation might be associated with a second event of illite growth and K-Ar ages of 96.5–106.7 Ma derived from the <0.2 μm fraction of the tight gas sandstones.This study demonstrates the exploration risk of fault-bound thermal anomalies by deteriorating entirely the reservoir quality of tight gas sandstones with respect to porosity and permeability due to the cementation with temperature-related authigenic cements. It documents that peak temperatures are not necessarily associated with peak subsidence. Consequently, these phenomena need to be considered in petroleum system models to avoid, for example, overestimates of burial depth and reservoir quality.  相似文献   

Bannu Basin,fold-and-thrust belt of northern Pakistan: Subsurface imaging and its implications for hydrocarbon exploration     

《Marine and Petroleum Geology》2017

The Trans Indus-Salt Range, located in northern Pakistan, is one of the most tectonically active fold-and-thrust belts and comprises three main regions: the Potwar-Salt Range, the Kohat-Surghar Range and the Bannu Basin-Khisor Range. Of these, the Bannu Basin is the least studied and only a handful of publically accessible datasets and publications are available. Recently made public 2D seismic profiles and well data from the Bannu Basin indicate the presence of salt as well as evidence for a main detachment surface which is Neoproterozoic in age. Our findings suggest that the Salt Range Formation could be the main detachment for the entire basin.Interpretation also shows a Miocene-Eocene basin-wide unconformity that marks the Himalayan orogenic event which separates the pre-Himalayan from the syn-Himalayan sedimentary units. On the basis of seismic reflection data, we conclude that the basin experienced three main tectonic settings. An early stage of pre-Himalayan passive tectonic environment is followed by the compressional Himalayan tectonics which resulted in uplifted areas sourcing the fluviatile fill of the subsided basin. During this time, sedimentation from the northern margin of the basin may have influenced the southward flow of salt. This is followed by a more recent stage of thrusting that produced folds and thrusts deforming all of the sedimentary units.Structural geometries suggest that prospective traps are developed mainly in the anticlines outlining the eastern and western boundaries of the Bannu Basin, as well as the southern zone of the basin. Furthermore, the presence of salt diapirism and transpression zones together with numerous oil seeps in and around the basin increase the probability of hydrocarbon accumulation and indicate great potential for future exploration.  相似文献   

The Paleogene vegetation and petroleum system in the tropics: A biomarker approach     

《Marine and Petroleum Geology》2017

The present study investigates the biomarker signatures of sediments and crude oils to infer the paleovegetation from the two petroleum systems of Assam Basin, eastern India. They are classified as the Paleocene-middle Eocene and the middle Eocene-Oligocene petroleum systems. The sediments are oil and gas prone with an early catagenetic stage of thermal evolution. Here we report tricyclic diterpanes such as rimuane, pimarane, rosane and isopimarane along with tetracyclic diterpanes: ent-beyerane, phyllocladane, kaurane from Paleocene-Eocene coal-bearing sediments and crude oils. These diterpane biomarkers attest dominant contribution from conifers, possibly from Podocarpaceae and Araucariaceae. However, diterpanes are not detected in Oligocene sediments and oils. Crude oils from both Paleocene-Eocene and Oligocene reservoirs and organic rich sediments contain angiosperm biomarkers such oleanane and related triterpanes along with bicadinane, a biomarker specific for the Dipterocarpaceae family of angiosperms. The equatorial position of India during early Paleogene along with the presence of angiosperm signatures including Dipterocarpaceae and gymnosperms reflect the emergence of tropical rainforest elements in eastern India. Absence of diterpenoids in Oligocene samples and difference in angiosperm parameters from Paleocene-Eocene samples suggests a change in source vegetation and organofacies.  相似文献   

Diagenetic model of the Bajo Barreal formation (Cretaceous) in the southwestern flank of the Golfo de San Jorge Basin (Patagonia, Argentina)     

《Marine and Petroleum Geology》2017

This paper analyses the diagenetic evolution of sandstones belonging to the Bajo Barreal Formation (Cretaceous) in the Golfo de San Jorge Basin (Patagonia, Argentina). The Bajo Barreal Formation includes the main reservoirs, which are located along the western area of the basin and is composed of sandstones, conglomerates, mudstones, tuffaceous mudstones and some layers of tuffs. The principal reservoirs comprise medium-to coarse-grained sandstones, which are dominated by feldspathic litharenites and contain minor amounts of litharenites and lithic arkoses. The authigenic minerals include kaolinite, smectite, chlorite, quartz overgrowths, microquartz and calcite, with minor proportions of megaquartz, siderite, analcime, laumontite, feldspar overgrowths and illite/smectite and chlorite/smectite mixed layers. Secondary porosity is much more important than primary porosity and is produced by the dissolution of feldspar, lithic clasts and clay cements. The diagenetic history of the Bajo Barreal sandstones can be divided into seven diagenetic stages, each of which is characterized by a specific assemblage of authigenic minerals and diagenetic processes. Eogenetic conditions occur in stages 1, 2, 3 and 4. Stage 1 corresponds to shallow burial characterized by the physical reduction of primary porosity by compaction; during stage 2, rim clay cements of chlorite, smectite and clinoptilolite, as well as thin quartz overgrowths, were formed. The precipitation of pore-filling cements of kaolinite, chlorite and smectite occurred during stage 3, while stage 4 records the intense dissolution of feldspar, lithic fragments and kaolinite cements. Mesogenesis occurs in diagenetic stages 5 and 6. The former corresponds to a new phase of authigenic kaolinite, while the latter records the significant dissolution of feldspar, lithic clasts and previous cements, which produced the highest values of secondary porosity. Finally, stage 7 corresponds to the highest degree of diagenesis in the Bajo Barreal Formation (mesogenesis), which resulted in the precipitation of cements of zeolites and calcite, as well as quartz and plagioclase overgrowths.  相似文献   

Basin modeling of the Late Miocene Zeit source rock in the Sudanese portion of Red Sea Basin: Implication for hydrocarbon generation and expulsion history     

《Marine and Petroleum Geology》2017

The Late Miocene Zeit Formation is exposed in the Red Sea Basin of Sudan and represents an important oil-source rock. In this study, five (5) exploratory wells along Red Sea Basin of Sudan are used to model the petroleum generation and expulsion history of the Zeit Formation. Burial/thermal models illustrate that the Red Sea is an extensional rift basin and initially developed during the Late Eocene to Oligocene. Heat flow models show that the present-day heat flow values in the area are between 60 and 109 mW/m². The variation in values of the heat flow can be linked to the raise in the geothermal gradient from margins of the basin towards offshore basin. The offshore basin is an axial area with thick burial depth, which is the principal heat flow source.The paleo-heat flow values of the basin are approximately from 95 to 260 mW/m², increased from Oligocene to Early Pliocene and then decreased exponentially prior to Late Pliocene. This high paleo-heat flow had a considerable effect on the source rock maturation and cooking of the organic matter. The maturity history models indicate that the Zeit Formation source rock passed the late oil-window and converted the oil generated to gas during the Late Miocene.The basin models also indicate that the petroleum was expelled from the Zeit source rock during the Late Miocene (>7 Ma) and it continues to present-day, with transformation ratio of more than 50%. Therefore, the Zeit Formation acts as an effective source rock where significant amounts of petroleum are expected to be generated in the Red Sea Basin.  相似文献